304 stainless steel stress corrosion cracking

Stress corrosion cracking facts and how to reduce the risk. Facts in brief about stress corrosion cracking scc stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. Nace corrosion 20 march 1721, 20 orlando, fl coastal salt effects on the stress corrosion cracking of type 304 stainless steel todd s. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Type 304 has good processability, weldability, corrosion resistance, heat resistance, low. The presence of 23 wt% molybdenum in the alloy makes the passive film stronger kain et al. Effect of halogens and inhibitors on the external stress. In these situations, 316 stainless steel is the correct choice. However, 304 stainless does not perform well in highsaline environments. Stress corrosion cracking in a brewery paul mueller company. Cracks were located mainly at positions close to the weld joint and the arc where very strong tensile residual stress existed.

Stress corrosion cracking susceptibility of irradiated. Mechanisms of stresscorrosion cracking asm international. This phenomenon has been responsible for incidents of rock climbing anchors breaking under minimal load in seaside areas, putting climbers. Chlorides can cause pitting, crevice corrosion, and stress corrosion cracking. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as applies to the insulation industry.

The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Mili24244 is a us dept of defense specification for insulation that is going to be used on the stainless steel pipe and equipment associated with nuclear propulsion. Chloride induced stress corrosion cracking of type 304 and. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Both 304 and 316 stainless steel types are resistant to a wide range of concentration and temperature.

Chloride stress corrosion cracking and 316 stainless steel. Pitting or crevice corrosion can occur on most stainless steel grades. This research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. Insitu monitoring of stress corrosion cracking of 304. The elbow was welded with two straight pipes at two ends. Stress corrosion cracking of an austenitic stainless steel. The datasheet and specification are summarized in the following tables including. Stress corrosion cracking of an austenitic stainless steel in. Type 304 stainless steel an overview sciencedirect topics. Below 80 degc they can be considered resistant to any concentration of sodium hydroxide, up to the limit of solubility. Effects of temperature and humidity on atmospheric stress. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. There is an additional risk of stress corrosion cracking scc at higher temperatures.

Stress corrosion cracking response of 304 stainless steel. On the stress corrosion cracking and hydrogen embrittlement. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. To understand the mechanisms behind chlorineinduced stress corrosion cracking ciscc in 304 stainless steel, synchrotron high energy xrays were use. Atmospheric stress corrosion cracking susceptibility. Practical solutions by solutions for people, processes and paper. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. Many times a good starting point is type 304 stainless because it is the most widely used stainless grade for increased corrosion resistance, move up to type 316 stainless, and for. Polythionic stress corrosion cracking of stainless steel tube environment. Atmospheric stress corrosion cracking of stainless steel rock. This results because of their similarity in nickel content. Stress corrosion also called stress corrosion cracking or chloride stress corrosion. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Stress corrosion cracking of austenitic stainless steel technical bulletin ind tb009 02212020 replaces 011918 two other common specifications are mili24244 and nrc 1.

Escc susceptibility depends on environmental factors. Chlorides are probably the single biggest enemy of stainless steel. Stresscorrosion cracking of sensitized type 304 stainless. The type 321 austenitic stainless steel is susceptible to stress corrosion cracking scc in halides similar to type 304 stainless steel. Mar 11, 2020 this research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. The scc susceptibility of sensitized type 304 stainless steel was studied using slow strain rate tests in 0.

Stress corrosion cracking of sensitized type 304 stainless. Scoping stress corrosion cracking scc tests of 304 stainless steel ss were performed in 75 c and 250 c aerated pressurized water apw and 250 c deaerated pressurized water dpw. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. The final, definitive version of this document can be found online at. The 250 c apw environment was used to initiate intergranular stress corrosion cracking igscc and then the water was deaerated and hydrogenated to see if igscc continued in 250 c dpw. Austenitic stainless steels crni types 304, 304l, 321, and similar and crnimo types 316, 316l, 316 ti, and similar are susceptible to atmosphericallyinduced stress corrosion cracking aiscc at ambient temperatures if hygroscopic salts such as mgcl 2 or cacl 2 are present on the surface and the air relative humidity rh is in a.

Corrosion developed after 4 weeks in the 304 and 304l specimens, and after 32 weeks in the 316l specimen. This mode of attack is termed stress corrosion cracking scc. External stress corrosion cracking escc by sea salt particles can occur in these plant component materials. A key question is the nature of irradiationassisted intergranular cracking at very high dose, i. Stainless steels are more resistant to general corrosion compared with carbon steel. It has been found that scc resistance can be improved in some cases with the application of compressive stress to the material at risk.

Stress corrosion cracking scc is a common issue with many specialty alloys. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. Unexpected corrosion of stainless steel in high solids black liquor service. Influence of high temperature on corrosion behavior of 304. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Next to water, chloride is the most common chemical found in nature. Unexpected corrosion of stainless steel in high solids black. Film and ph effects in the stress corrosion cracking of. Hence the tendency for stress corrosion cracking of the plain 304 or 316 stainless steels in solution annealed condition is not considered to be different from its low carbon varieties. Stress corrosion cracking response of 304 stainless steel in. Stress corrosion cracking facts and how to reduce the.

Irradiationinduced stress corrosion cracking of austenitic. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. In situ synchrotron xray tomography of 304 stainless. Austenitic stainless steels crni types 304, 304l, 321, and similar and crnimo types 316, 316l, 316 ti, and similar are susceptible to atmosphericallyinduced stress corrosion cracking aiscc at ambient temperatures if hygroscopic salts such as mgcl 2 or cacl 2 are present on the surface and the air relative humidity rh is in a critical range.

A film of more acidic corrodent solution is raised to ph 1. There is an additional risk of stress corrosion cracking scc at. Atmospheric stress corrosion cracking susceptibility of. Rapid stress corrosion cracking of 304 stainless steel in mgcl 2fecl 3 solutions at 125 c has been shown to occur only when the ph of the corrodent liquid within the crack lay between 1. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. In order to demonstrate the improvement of the scc resistance of the welded joints, the specimens were immersed in boiling 42% magnesium chloride solution during scc testing, and untreated specimen cracked after immersion. We examined the effects of temperature and humidity on escc experimentally. Polythionic stress corrosion cracking of stainless steel tube. There can be a risk of stress corrosion cracking scc attack at higher temperatures, which is common to both the 304 and. Stress corrosion cracking scc of 304 stainless steel ss in hightemperature water was insitu monitored by analyzing acoustic emission ae waveform. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry.

The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. In this work, hotcell tests and micro structural characterization were performed on type 304 ss from the hexagonal fuel can of the decommissioned ebrii reactor after. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Pdf chloride induced stress corrosion cracking of type 304.

This diagram figure 1 is analogous to a similar diagram for caustic. Potentialtemperature domains in which purely igscc, simultaneous igscc and tgscc, and igscc accompanied by pitting corrosion have been. Analysis of initiation and propagation of stress corrosion. The stress corrosion cracking scc behavior of sensitized type 304 stainless steel was studied in 288 deg c primary water as a function of oxygen and fluoride contents of the water, stress level, prestrain, heat treatment, and surface preparation tarnish film, surface ground, or pickled. Both of type 304 and type 316 stainless steels showed quite similar. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.

The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. In most environments, the ppm are so small the effects on stainless are minute. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0. Ss304 grade aisi 304 stainless steel properties, composition. Jan 08, 2002 the duplex stainless steels, on the other hand, are more resistant to stress corrosion cracking scc than austenitic grades. Stress corrosion cracking of a 304 stainless steel elbow. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization.

Stress corrosion cracking susceptibility of irradiated type. The residual stress distribution of the aisi 304 stainless steel induced by uit was predicted by finite element analysis. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. For more information, please check 304 vs 316 stainless steel. Stresscorrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing conditions in the water. Apr 30, 2007 scoping stress corrosion cracking scc tests of 304 stainless steel ss were performed in 75 c and 250 c aerated pressurized water apw and 250 c deaerated pressurized water dpw. The molybdenum added to 316 stainless increases the corrosion resistance to chlorides like sea water and deicing salts. Stress corrosion cracking of type 304 austenitic stainless. Mar 04, 2020 the second test conducted, the salt fog test, was expected to closely simulate field conditions around dry cask containers, and resulted in stress corrosion cracking and pitting corrosion in all the 43 c 109 f specimens. Stress corrosion cracking scc of duplex stainless steel.

Austenitic stainless steels are widely used as structural materials for chemical and power plants. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Slowstrainrate tensile tests and microstructural analysis by auger electron spectroscopy were conducted on specimens of high and commercialpurity hp and cp heats of type 304 stainless steel obtained from neutron absorber tubes and a control blade sheath after irradiation up to 2. Pitting and crevice corrosion stress corrosion cracking. Unexpected corrosion of stainless steel in high solids. Chloride stress corrosion cracking in austenitic stainless. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Effect of ultrasonic impact treatment on the stress. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design.

Effects of fluoride and other halogen ions on the external. Transgranular stress corrosion cracking of 304l stainless. Film and ph effects in the stress corrosion cracking of type. Aisi 304 grade stainless steel uns s30400 aisi 304 stainless steel uns s30400 is the most commonly used material in stainless steels, and is usually purchased in an annealed or cold worked state. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Several scc modes including transgranular scc tgscc, intergranular scc igscc and mixture of tgscc and igscc were obtained by changing material state and controlling load mode, dissolved oxygen concentration. Aisi 304l is the low carbon version of 304 stainless steel, aisi 316 is better than grade 304 in certain properties, corrosion resistance and heat resistance, etc. Stress corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. The general pattern of the observed failures indicates that as nuclear plants age and fluence. Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and temperatures. Because ss 304 contains 18% chromium cr and 8% nickel ni, its also known as 188 stainless steel.